2024-03-28T21:54:56Zhttps://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/381032021-06-24T07:43:37Zcom_10324_28542com_10324_952com_10324_894com_10324_1187com_10324_931col_10324_28543col_10324_1408
UVaDOC
author
Gutiérrez Loriente, Agustín
author
Martín Álvarez, José Miguel
author
Prieto, Elena
author
Andrés Juan, Celia
author
Nieto Román, Francisco Javier
2019-09-24T10:35:37Z
2019-09-24T10:35:37Z
2019
Advanced Synthesis and Catalysis, Volume361, Issue 5, 2019 Pages 1042-1063
1615-4150
http://uvadoc.uva.es/handle/10324/38103
10.1002/adsc.201801454
1042
5
1063
Advanced Synthesis & Catalysis
361
Diastereoselective ring‐closing metathesis reactions on chiral trienic perhydro‐1,3‐benzoxazines derived from (−)‐8‐aminomenthol featuring two diastereotopic olefin chains is described. The diastereochemical outcome of the cyclization appeared to be dependent on the length and position of the olefin chains in perhydro‐1,3‐benzoxazine, the degree of substitution of the double bonds and the ruthenium catalyst used. After separation of the diastereomers, and removal of the chiral auxiliary, enantiopure oxygen‐ and nitrogen‐containing heterocycles were obtained.
eng
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Synthesis of Enantiopure Oxygen- and Nitrogen-Containing Heterocycles by Diastereoselective Ring-Closing Metathesis Reaction in Perhydro-1,3-benzoxazine Derivatives
info:eu-repo/semantics/article
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b3IgaW5jdW1wbGltaWVudG8gZGUgY3VhbHF1aWVyYSBkZSBsYXMgb2JsaWdhY2lvbmVzIGRlcml2YWRhcyBkZWwgQWN1ZXJkbywgcG9yIHZvbHVudGFkIGV4cHJlc2EgZGVsIEF1dG9yCkVuICBwcnVlYmEgZGUgY29uZm9ybWlkYWQsIGxhcyBwYXJ0ZXMgYWNlcHRhbiBlbCBwcmVzZW50ZSBBY3VlcmRvCgoKCgo=
URL
https://uvadoc.uva.es/bitstream/10324/38103/1/Synthesis-Enantiopure-Oxygen.pdf
File
MD5
5199e294b4c69bdaf62f8ee12254fcb0
906791
application/pdf
Synthesis-Enantiopure-Oxygen.pdf