2026-06-13T03:26:46Zhttps://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/653742024-01-30T20:03:08Zcom_10324_28708com_10324_954com_10324_894com_10324_28542com_10324_952com_10324_1186com_10324_931col_10324_28709col_10324_28543col_10324_1404
UVaDOC
author
Barbero San Juan, Héctor
author
Masson, Eric
2024-01-30T15:25:27Z
2024-01-30T15:25:27Z
2021
Chem. Sci., 2021, 12, 9962
2041-6520
https://uvadoc.uva.es/handle/10324/65374
10.1039/d1sc02637b
9962
29
9968
Chemical Science
12
2041-6539
Platinum terpyridyl complexes, stacked on top of one another and secured as dimers with cucurbit[8]uril (CB[8]) in aqueous medium, were functionalized quantitatively and in situ with a pair of pentapeptides Phe-(Gly)3-Cys by grafting their cysteine residues to the Pt centers. The resulting CB[8]·(Pt·peptide)2 assemblies were used to target secondary hosts CB[7] and CB[8] via their pair of phenylalanine residues, again in situ. A series of well-defined architectures, including a supramolecular “pendant necklace” with hybrid head-to-head and head-to-tail arrangements inside CB[8], were obtained during the self-sorting process after combining only 3 or 4 simple building units.
eng
Attribution-NonCommercial-NoDerivs 3.0 Unported
Design and recognition of cucurbituril-secured platinum-bound oligopeptides
info:eu-repo/semantics/article
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IApwb3IgaW5jdW1wbGltaWVudG8gZGUgY3VhbHF1aWVyYSBkZSBsYXMgb2JsaWdhY2lvbmVzIGRlcml2YWRhcyBkZWwgQWN1ZXJkbywgcG9yIHZvbHVudGFkIGV4cHJlc2EgZGVsIEF1dG9yCkVuICBwcnVlYmEgZGUgY29uZm9ybWlkYWQsIGxhcyBwYXJ0ZXMgYWNlcHRhbiBlbCBwcmVzZW50ZSBBY3VlcmRvCgoKCgo=
URL
https://uvadoc.uva.es/bitstream/10324/65374/1/Masson%20-%20ChemSci%20-%20Design%20and%20recognition%20of%20cucurbituril.pdf
File
MD5
d50b7265d654f9e53b243db23e5684a4
977915
application/pdf
Masson - ChemSci - Design and recognition of cucurbituril.pdf