2024-03-29T00:59:10Zhttps://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/226652022-03-01T10:47:10Zcom_10324_1186com_10324_931com_10324_894col_10324_1404
Pérez, Cristóbal
Mata López, Santiago
Cabezas, Carlos
López, Juan Carlos
Alonso Hernández, José Luis
2017-03-20T12:58:46Z
2017-03-20T12:58:46Z
2015
Journal of Physical Chemistry A, 2015, 119 (16), pp 3731–3735
http://uvadoc.uva.es/handle/10324/22665
10.1021/acs.jpca.5b01792
Journal of Physical Chemistry A
In this work neutral tyrosine has been generated in the gas phase by laser ablation of solid samples, and its most abundant conformers characterized through their rotational spectra. Their identification has been made by comparison between the experimental and ab initio values of the rotational and quadrupole coupling constants. Both conformers are stabilized by an O–H•••N hydrogen bond established within the amino acid skeleton chain and an additional weak N–H•••π hydrogen bond. The observed conformers differ in the orientation of the phenolic −OH group.
eng
info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
© American Chemical Society
Attribution-NonCommercial-NoDerivatives 4.0 International
The Rotational Spectrum of Tyrosine
info:eu-repo/semantics/article