2024-03-19T04:24:26Zhttps://uvadoc.uva.es/oai/requestoai:uvadoc.uva.es:10324/479152021-09-10T09:12:58Zcom_10324_1186com_10324_931com_10324_894col_10324_1404
Alonso Alonso, Elena Rita
35431952e388e6f0
600
León Ona, Iker
85de6a07bb57ac2a
600
Kolesnikova, Lucie
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600
Mata, Santiago
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600
Alonso Hernández, José Luis
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0000-0002-3146-8250
2021-08-19T10:25:43Z
2021-08-19T10:25:43Z
2021
Angewandte Chemie International Edition, 2021, vol. 60, n. 32, p. 17410-17414
1433-7851
https://uvadoc.uva.es/handle/10324/47915
10.1002/anie.202105718
17410
32
17414
Angewandte Chemie International Edition
60
1521-3773
Producción Científica
The unbiased, naked structures of tartaric acid, one of the most important organic compounds existing in nature and a candidate to be present in the interstellar medium, has been revealed in this work for the first time. Solid samples of its naturally occurring (R,R) enantiomer have been vaporized by laser ablation, expanded in a supersonic jet, and characterized by Fourier transform microwave spectroscopy. In the isolation conditions of the jet, we have discovered up to five different structures stabilized by intramolecular hydrogen-bond networks dominated by O−H⋅⋅⋅O=C and O−H⋅⋅⋅O motifs extended along the entire molecule. These five forms, two with an extended (trans) disposition of the carbon chain and three with a bent (gauche) disposition, can serve as a basis to represent the shape of tartaric acid. This work also reports the first set of spectroscopy data that can be used to detect tartaric acid in the interstellar medium.
Ministerio de Ciencia e Innovación (CTQ2016- 76393-P y PID2019-111396GB-I00)
Junta de Castilla y León (Subvenciones VA077U16 y VA244P20)
application/pdf
eng
Wiley
info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
© 2021 The Authors
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Ácido tartárico
Tartaric acid
Espectroscopia rotacional
Rotational spectroscopy
2210 Química Física
2303 Química Inorgánica
Unveiling five naked structures of tartaric acid
info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202105718
SI
THUMBNAIL
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Unveiling-five-naked-structures.pdf
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2021-09-10 11:12:58.305
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