RT info:eu-repo/semantics/article
T1 Dramatic Mechanistic Switch in Sn/AuI Group Exchanges: Transmetalation vs. Oxidative Addition
A1 García Melchor, Max
A1 Casares González, Juan Ángel
A1 Espinet Rubio, Pablo
K1 Reacciones químicas
AB The mechanism of Ph/X exchange in reactions involving SnPhnBu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an AuIII intermediate when X = vinyl.
PB Royal Society of Chemistry
SN 1364-548X
YR 2016
FD 2016
LK http://uvadoc.uva.es/handle/10324/17026
UL http://uvadoc.uva.es/handle/10324/17026
LA eng
NO Chem. Commun., 2016, 52, 4305-4308
NO Producción Científica
DS UVaDOC
RD 27-dic-2024