RT info:eu-repo/semantics/article
T1 Chiral Ureas and Thioureas Supported on Polystyrene for Enantioselective Aza-Henry Reaction in Solvent-free conditions
A1 Pedrosa Sáez, Rafael
A1 Andrés García, José María
A1 Ávila, Deisy P.
A1 Ceballos, Miriam
A1 Pindado Hernández, Rodrigo
K1 Catalizadores
K1 Química orgánica
AB Novel bifunctional ureas and thioureas inmovilized on sulfonylpystyrene have been prepared as recoverable and reusable organocatalysts and used in the stereoselective aza-Henry reaction under solvent-free conditions. The activity and stereoselection of the catalysts are dependent on the length of the tether bringing the active site and the polymer, being the catalyst derived from 1,6-hexane diamine the best one. It has been also demonstrated that the supported catalysts are more effective than the homologous soluble catalysts.
PB Royal Society of Chemistry
SN 1463-9262
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/21447
UL http://uvadoc.uva.es/handle/10324/21447
LA eng
NO Green Chemistry, 2015, vol.17, p. 2217-2225
NO Producción Científica
DS UVaDOC
RD 24-nov-2024