RT info:eu-repo/semantics/article
T1 7-Endo selenocyclization reactions on chiral 3-prenyl and 3-cinnamyl-2 hydroxymethylperhydro-1,3-benzoxazine derivatives. A way to enantiopure 1,4-oxazepanes
A1 Nieto Román, Francisco Javier
A1 Andrés Juan, Celia
A1 Pérez Encabo, Alfonso
K1 Química orgánica
AB Enantiopure 1,4-oxazepanes derivatives have been prepared by selenocyclofunctionalization of chiral 3-prenyl- and 3-cinnamyl-2-hydroxymethyl-substituted perhydro-1,3-benzoxazine derivatives. The 7-endo-cyclization occurs in high yields and diastereoselection. The regio and stereochemistry of the cyclization products was dependent of the substitution pattern of the double bond, the nature of the hydroxyl group and the experimental conditions.
PB Royal Society of Chemistry
SN 1477-0520
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/21450
UL http://uvadoc.uva.es/handle/10324/21450
LA eng
NO Organic & Biomolecular Chemistry, 2015,13, p. 9118-9126
NO Producción Científica
DS UVaDOC
RD 24-nov-2024