RT info:eu-repo/semantics/article
T1 Enantioselective Synthesis of Seven-Membered Carbo- and Heterocyles by Organocatalyzed Intramolecular Michael Addition
A1 Guevara Pulido, James Oswaldo
A1 Andrés García, José María
A1 Ávila, Deisy P.
A1 Pedrosa Sáez, Rafael
K1 Química orgánica
AB Unprecedented diastereo- and enantioselective synthesis of seven-membered rings has been achieved by organocatalyzed intramolecular Michael addition of enals bearing β-diketone functionality. The cyclization leads to 2,3-disubstituted cycloheptanone derivatives in high yield and excellent stereoselectivity. The same organocatalyzed cyclization process has been used to prepare six-membered homologs, but with lower stereoselectivity.
PB Royal Society of Chemistry
YR 2016
FD 2016
LK http://uvadoc.uva.es/handle/10324/21452
UL http://uvadoc.uva.es/handle/10324/21452
LA eng
NO RSC Advances, 2016, 6, p. 30166-30169
NO Producción Científica
DS UVaDOC
RD 22-nov-2024