RT info:eu-repo/semantics/article
T1 The stille reaction, 38 years later
A1 Cordovilla, Carlos
A1 Bartolomé Albistegui, María del Camino
A1 Martínez de Ilarduya Martínez de Ilarduya, Jesús María
A1 Espinet Rubio, Pablo
K1 Stille cross-coupling
AB The first now named Stille reaction was published 38 years ago, andthe last comprehensive revision of this catalysis was in 2004. Since then theknowledge of the different steps of the three possible (and sometimes competing)reaction pathways (cyclic, open, and ionic) has been almost completed by synergisticexperimental and theoretical studies: the Stille reaction is perhaps the best characterizedcatalytic process if we consider the number of intermediates that havebeen detected. This review concentrates on the mechanistic new knowledge, andon important aspects as the revolution with the use of bulky phosphines, the bimetallicalternative of the Stille reaction, the enantioselectivity in Stille and palladiumfree Stille processes, the meaning of copper effect, or the possible approaches tomake Stille coupling a greener process.
PB American Chemical Society
SN 2155-5435
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/21709
UL http://uvadoc.uva.es/handle/10324/21709
LA eng
NO ACS Catalysis 2015, 5 (5), p. 3040–3053
NO Producción Científica
DS UVaDOC
RD 22-nov-2024