RT info:eu-repo/semantics/article
T1 Formal Gold to Gold Transmetalation of an Alkynyl Group Mediated by Palladium: A Bisalkynyl Gold Complex as a Ligand to Palladium
A1 Toledo Pérez, Alberto
A1 Meana, Isabel
A1 Albéniz Jiménez, Ana Carmen
K1 Palladium
AB The reaction of [Au(C≡CnBu)]n with [Pd(η3-allyl)Cl(PPh3)]results in a ligand and alkynyl rearrangement, and leads to the heterometallic complex [Pd(η3-allyl){Au(C≡CnBu)2}]2 (3) with an unprecedented bridging bisalkynyl gold ligand coordinated to palladium. This is a formal gold to gold transmetalation that occurs through reversible alkynyl transmetalations between gold and palladium.
PB American Chemical Society
SN 2155-5435
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/21711
UL http://uvadoc.uva.es/handle/10324/21711
LA eng
NO Chemistry - A European Journal, 2015, Volume 21, Issue 38, p. 13216–13220
NO Producción Científica
DS UVaDOC
RD 03-ene-2025