RT info:eu-repo/semantics/article
T1 Cross Alkyl-Aryl Versus Homo Aryl-Aryl Coupling in Pdcatalyzed Coupling of Alkyl-Gold(I) and Aryl-X (X = Halide)
A1 Carrasco Fernández, Desiré
A1 Pérez Temprano, Mónica H.
A1 Casares González, Juan Ángel
A1 Espinet Rubio, Pablo
K1 Catalyst
AB Experiments on palladium catalyzed cross-coupling of [AuMe(PPh3)] with aryl iodides show that Ar–Ar homocoupling products are the main product or an abundant byproduct of the reaction. The percentage of cross-coupling product is higher for aryls with larger p Hammet parameter. The scrambling of organic groups via bimetallic intermediates explains the formation of these products. This scrambling can be observed and the activation energies partially quantified in some cases using as aryl C6Cl2F3, which is relatively reluctant to coupling.
PB American  Chemical Society
SN 0276-7333
YR 2014
FD 2014
LK http://uvadoc.uva.es/handle/10324/21728
UL http://uvadoc.uva.es/handle/10324/21728
LA eng
NO Organometallics, 2014, 33 (13), p. 3540–3545
NO Producción Científica
DS UVaDOC
RD 24-nov-2024