RT info:eu-repo/semantics/article
T1 Asymmetric Organocatalysts Supported on Vinyl Addition Polynorbornenes for Work in Aqueous Media
A1 Sagamanova, Irina K.
A1 Sayalero Sanz, Sonia
A1 Martínez Arranz, Sheila
A1 Albéniz Jiménez, Ana Carmen
A1 Pericàs, Miquel A.
K1 Organic Chemistry
AB In an effort to identify novel polymer architectures suitable for the covalent supporting of catalysts, L–proline derivatives have been immobilized onto rationally designed vinyl addition polynorbornene (VA-PNB) resins through copper-catalyzed azide-alkyne cycloaddition (CuAAC) reactions. The fully saturated VA-PNB resins have been found to be optimal catalyst supports, the resulting proline-functionalized resins behaving as very active, easily recoverable and highly reusable organocatalysts for the asymmetric direct aldol reaction of benzaldehydes with ketones in aqueous media. The obtained results show that the combination of modular,VA-PNB resins with proline derivatives through triazole linkers represent a promising strategy for the immobilization of organocatalytic species.
PB The Royal Society of Chemistry
SN 2044-4753
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/21741
UL http://uvadoc.uva.es/handle/10324/21741
LA eng
NO Catalysis Science and Technology, 2015,5, p. 754-764
NO Producción Científica
DS UVaDOC
RD 24-nov-2024