RT info:eu-repo/semantics/article
T1 Generation and structural characterization of aluminum cyanoacetylide
A1 Cabezas, Carlos
A1 Barrientos Benito, María Carmen
A1 Largo Cabrerizo, Antonio
A1 Guillemin, Jean-Claude
A1 Cernicharo, José
K1 Espectroscopia de microondas
K1 Moléculas
AB Combined spectroscopy measurements and theoretical calculations bring to light a first investigation of a metallic cyanoacetylide, AlC3N, using laser ablation molecular beam Fourier transform microwave spectroscopy. This molecule was synthesized in a supersonic expansion by the reaction of aluminum vapour with C3N, produced from solid aluminum rods and BrCCCN in a newly constructed ablation-heating nozzle device. A set of accurate rotational and 27Al and 14N nuclear quadrupole coupling constants have been determined from the analysis of the rotational spectrum and compared with those predicted in a high-level ab initio study, conducting to the assignment of the observed species to linear AlCCCN. We have searched for this species towards the carbon-rich evolved star IRC + 10216 but only an upper limit to its abundance has been obtained.
PB AIP Publishing
SN 0021-9606
YR 2014
FD 2014
LK http://uvadoc.uva.es/handle/10324/22510
UL http://uvadoc.uva.es/handle/10324/22510
LA eng
NO The Journal of Chemical Physics 141, 104305 (2014)
NO Producción Científica
DS UVaDOC
RD 27-jul-2024