RT info:eu-repo/semantics/article
T1 Metallic Cyanoacetylides of Copper, Silver and Gold: Generation and Structural Characterization
A1 Cabezas, Carlos
A1 Barrientos Benito, María Carmen
A1 Largo Cabrerizo, Antonio
A1 Guillemin, Jean-Claude
A1 Alonso Hernández, José Luis
K1 Química física
AB The metallic cyanoacetylides CuCCCN, AgCCCN, and AuCCCN have been synthesized in the throat of a pulsed supersonic expansion by reaction of metal vapors, produced by laser ablation, and BrCCCN. Their pure rotational spectra in the (X1Σ+) electronic ground state were observed by Fourier transform microwave spectroscopy in the 2-10 GHz frequency region. Importantly, the rotational spectroscopy constants determined from the analysis of the rotational spectra clearly established the existence of metal-CCCN arrangements for all the mentioned cyanoacetylides. A study of the chemical bonding by means of a topological analysis of the electron density helps to understand the preference for metal-C bonding over metal-N bonding.
PB Royal Society of Chemistry
SN 1463-9076
YR 2016
FD 2016
LK http://uvadoc.uva.es/handle/10324/22623
UL http://uvadoc.uva.es/handle/10324/22623
LA eng
NO Physical Chemistry Chemical Physics 2016 Oct 19;18 (41), p. 28538-28547
NO Producción Científica
DS UVaDOC
RD 25-abr-2024