RT info:eu-repo/semantics/article
T1 Furanosic forms of sugars: conformational equilibrium of methyl beta-D-ribofuranoside
A1 Écija, Patricia
A1 Uriarte, Iciar
A1 Spada, Lorenzo
A1 Davis, Benjamin
A1 Caminati, Walther
A1 Basterretxea, Francisco José
A1 Lesarri Gómez, Alberto Eugenio
A1 Cocinero, Alberto
K1 Química
AB The investigation of an isolated ribofuranose unit in the gas phasereveals the intrinsic conformational landscape of the biologicallyactive sugar form.We report the rotational spectra of two conformersof methyl b-D-ribofuranoside in a supersonic jet expansion. Bothconformers adopt a near twisted (3T2) ring conformation with themethoxy and hydroxymethyl substituents involved in various intramolecularhydrogen bonds.
PB Royal Society of Chemistry
SN 1359-7345
YR 2016
FD 2016
LK http://uvadoc.uva.es/handle/10324/23472
UL http://uvadoc.uva.es/handle/10324/23472
LA spa
NO ChemComm, 2016, 52, 6241
DS UVaDOC
RD 25-nov-2024