RT info:eu-repo/semantics/article
T1 Determination of density and excess molar volume of dimethyl sulfoxide+1-allyl-3-methylimidazolium chloride mixtures at high pressure
A1 Pablo Nisa, Laura de
A1 Segovia Puras, José Juan
A1 Martín Martínez, Ángel
A1 Martín González, María del Carmen
A1 Bermejo Roda, Maria Dolores
K1 Densidades
K1 Ionic Liquid
K1 1-Ally-3-methylimidazolium chloride
K1 dimethyl sulfoxide
K1 Density
K1 Excess Molar Volume
K1 Correlation
AB In this work, densities of dimethyl sulfoxide + 1-allyl-3-methylimidazolium chloride mixtures have been experimentally determined with a vibrating tube densimeter. Densities were measured at temperatures between 293.15 and 373.15 K and molar fractions of dimethyl sulfoxide xDMSO = 0, 0.05, 0.1, 0.15, 0.25, 0.5, 0.75, 0.9 and 1 at pressures in the range P = [0.1, 35] MPa. It was found that density increases with ionic liquid concentration and with pressure and decrease with temperature. Excess molar volumes were calculated resulting in negative values with a maximum of non-ideality at DMSO concentration of xDMSO = 0.5. The excess molar values were less negative at high pressures. At T = 330 K a maximum in the excess molar values was observed at several concentrations. Density was correlated as a function of temperature, pressure and concentration with an average relative deviation of 0.12%.
PB Elsevier B.V.
SN 0896-8446
YR 2017
FD 2017
LK http://uvadoc.uva.es/handle/10324/26143
UL http://uvadoc.uva.es/handle/10324/26143
LA spa
NO The Journal of Supercritical Fluids, Volume 130, December 2017, Pages 76-83
NO Producción Científica
DS UVaDOC
RD 24-nov-2024