RT info:eu-repo/semantics/article
T1 ReI(CO)3 complexes with diimine ligands synthesized in situ
A1 Villafañe González, Fernando
K1 Química
K1 coordination chemistry
K1 Coupling reactions
K1 Diimines
K1 In situ synthesis
K1 Rhenium
K1 Tridentate ligands
AB This work covers the coupling reactions of monodentate ligands coordinated to the ‘‘ReI(CO)3” moiety to afford in situ new bidentate diimine ligands. Similar reactions leading to tridentate ligands are also included. The reactions reviewed present evident advantages respect to the usual synthetic methods of these ligands. Besides, choosing the appropriate substituents allows an easy tuning of the properties of the final complexes. Following an approximate chronological order, the formation of bidentate ligands by C-N coupling from a coordinated carbonyl group, from diiminoisoindoline, and the formation of amidino ligands from nitriles are reviewed first. This is followed by the formation of bidentate ligands by C-C coupling, and finally by the formation of tridentate ligands, either by C-C coupling, by B-N coupling, or by using ‘‘click” reactions.
PB Elsevier
SN 0010-8545
YR 2017
FD 2017
LK http://uvadoc.uva.es/handle/10324/28714
UL http://uvadoc.uva.es/handle/10324/28714
LA eng
NO Coordination Chemistry Reviews, 2017, Volume 339, Pages 128-137
NO Producción Científica
DS UVaDOC
RD 23-dic-2024