RT info:eu-repo/semantics/article
T1 Hidden aryl-exchange processes in stable 16e RhIII [RhCp*Ar2] complexes, and their unexpected transmetalation mechanism
A1 Peñas de Frutos, Marconi Nicolás
A1 Bartolomé Albistegui, María del Camino
A1 García Melchor, Max
A1 Espinet Rubio, Pablo
K1 Transmetalación
AB Experiments mixing the stable 16e 5-coordinate complexes [RhCp*Ar2] (Cp* = C5Me5; Ar = C6F5, C6F3Cl2-3,5) uncover fast aryl transmetalations. Unexpectedly, as supported computationally, these exchanges are not spontaneous, but catalyzed by minute amounts of 18e (μ-OH)2[RhCp*Ar]2 as a source of 16e [RhCp*Ar(OH)]. The OH group is an amazingly efficient bridging partner to diminish the activation barrier of transmetalation.
PB Royal Society of Chemistry
SN 1359-7345
YR 2018
FD 2018
LK http://uvadoc.uva.es/handle/10324/28845
UL http://uvadoc.uva.es/handle/10324/28845
LA eng
NO Chemical Communications, 2018, 54, 8, p. 984-987
NO Producción Científica
DS UVaDOC
RD 11-dic-2024