RT info:eu-repo/semantics/article
T1 Multivalent Molecular Shuttles – Effect of Increasing the Number of Centers in Switchable Catalysts
A1 Álvarez González, Celedonio Manuel
A1 Barbero San Juan, Héctor
A1 Miguel San José, Daniel
K1 Organocatalysis
AB A family of three molecular shuttles based upon ammonium/triazolinium salt motifs with one, two, and three catalytic centers were prepared along with their corresponding non‐interlocked threads. The switching process for all rotaxanes was tested through an in situ procedure in solution. Furthermore, their organocatalysis of two Michale‐type reactions by iminium activation was tested to check whether the increase of the number of catalytic centers in the same shuttle is a decisive factor to improve their efficiencies compared with those of single‐active‐site organocatalytic shuttles under the same conditions.
PB Wiley
SN 1434-193X
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/29160
UL http://uvadoc.uva.es/handle/10324/29160
LA eng
NO European Journal of Organic Chemistry, 2015, 6631–6640
NO Producción Científica
DS UVaDOC
RD 22-dic-2024