RT info:eu-repo/semantics/article
T1 Assembling Nonplanar Polyaromatic Units by Click Chemistry. Study of Multicorannulene Systems as Host for Fullerenes
A1 Álvarez González, Celedonio Manuel
A1 Aullón, Gabriel
A1 Barbero San Juan, Héctor
A1 García Escudero, Luis Ángel
A1 Martínez Pérez, Cristina
A1 Martín Álvarez, José Miguel
A1 Miguel San José, Daniel
AB Novel compounds with two or three corannulene subunits have been obtained by “click chemistry”. These exotic systems were synthesized in high yields using the ethynylcorannulene as common reagent. The synergistic action as receptors for fullerenes of several corannulene blocks has been evaluated. It was found that the three-armed derivatives showed efficient complexation abilities toward C60. Furthermore, a new compound having two corannulene subunits linked to a hexahelicene scaffold has a remarkable affinity constant. Finally, theoretical calculations have been performed to evaluate the formation of their relative adducts containing a C60 molecule.
PB American Chemical Society
SN 1523-7060
YR 2015
FD 2015
LK http://uvadoc.uva.es/handle/10324/29162
UL http://uvadoc.uva.es/handle/10324/29162
LA eng
NO Organic Letters 2015, 17 (11), pp 2578–2581
NO Producción Científica
DS UVaDOC
RD 04-dic-2024