RT info:eu-repo/semantics/article T1 Array of biosensors for discrimination of grapes according to grape variety, vintage and ripeness. A1 Rodríguez Méndez, María Luz A1 Medina Plaza, Cristina A1 Saja Sáez, José Antonio de A1 Fernández Escudero, José Antonio A1 Barajas Tola, Enrique A1 Medrano, Germán AB A bioelectronic tongue based on nanostructured biosensors specific for the simultaneous detection of sugars and phenols has been developed. The array combined oxidases and dehydrogenases immobilized on a lipidic layer prepared using the Langmuir-Blodgett technique where Glucose oxidase, d-Fructose dehydrogenase, Tyrosinase or Laccase were imbibed. A phthalocyanine was co-immobilized in the sensing layer and used as electron mediator. The array thus formed has been used to analyze grapes and provides global information about the samples while providing specific information about their phenolic and their sugar content. Using Principal Component Analysis (PCA) the array of voltammetric biosensors has been successfully used to discriminate musts prepared from different varieties of grapes (Tempranillo, Garnacha, Cabernet-Sauvignon, Prieto Picudo and Mencía). Differences could be also detected between grapes of the same variety and cultivar harvested in two successive vintages (2012 and 2013). PB Universidad de Valladolid EII YR 2016 FD 2016 LK http://uvadoc.uva.es/handle/10324/30564 UL http://uvadoc.uva.es/handle/10324/30564 LA spa NO Analytica Chimica Acta 2016, vol.947 p. 16-22 DS UVaDOC RD 22-dic-2024