RT info:eu-repo/semantics/article
T1 Improving the extensional rheological properties and foamability of HDPE by means of chemical crosslinking
A1 Rodríguez Méndez, María Luz
A1 Laguna Gutiérrez, Ester
A1 Pinto Sanz, Javier
A1 Kumar, Vipin
A1 Rodríguez Pérez, Miguel Ángel
AB Obtaining high-density polyethylene-based microcellular foams is a topic of interest due to the synergistic properties that can be obtained by the fact of achieving a microcellular structure using a polymer with a high number of interesting properties. However, due to the high crystallinity of this polymer, the production of low-density microcellular foams, by a physical foaming process, is not a simple task. In this work, the proposed solution to produce these materials is based on using crosslinked high-density polyethylenes. By crosslinking the polymer matrix, it is possible to increase the amount of gas available for foaming and also to improve the extensional rheological properties. In addition, the foaming time and the foaming temperature have also been modified with the aim of analyzing and understanding the mechanisms taking place during the foaming process to finally obtain cellular materials with low densities and improved cellular structures. The results indicate that cellular materials with relative densities of 0.37 and with cell sizes of approximately 2 µm can be produced from crosslinked high-density polyethylene using the appropriate crosslinking degree and foaming parameters.
YR 2016
FD 2016
LK http://uvadoc.uva.es/handle/10324/30582
UL http://uvadoc.uva.es/handle/10324/30582
LA eng
NO Journal of Cellular Plastics
DS UVaDOC
RD 27-dic-2024