RT info:eu-repo/semantics/article
T1 Benzylic Complexes of Palladium(II): Bonding modes and Penta- coordination for Steric Relief
A1 Martín Ruiz, Blanca
A1 Pérez Ortega, Ignacio
A1 Albéniz Jiménez, Ana Carmen
K1 Chemistry
K1 Organometallic Chemistry
K1 Palladium
K1 Benzyl complexes
AB A large variety of α-(pentafluorophenylmethyl)benzylic palladium complexes with different ligands have been synthesized and char- acterized. Multinuclear NMR spectroscopic data allow to determine the σ-or η3-benzylic nature of the complexes in solution. The adoption of either coordination mode is a function of the number of ligands coordinated to palladium and, remarkably, the presence of bulky phosphines favors the adoption of a bidentate η3-benzylic mode and palladium pentacoordinated complexes. Experimental data and DFT calculations indicate that this five- coordination could alleviate the steric hindrance of two cis bulky phosphines. The benzylic complexes show a rich fluxional behavior that involves both ligand exchange and σ- to η3-benzylic interconversion.
PB American Chemical Society
YR 2018
FD 2018
LK http://uvadoc.uva.es/handle/10324/31462
UL http://uvadoc.uva.es/handle/10324/31462
LA eng
NO Organometallics, 2018, Vol. 37, p. 1074-1085
DS UVaDOC
RD 22-dic-2024