RT info:eu-repo/semantics/article
T1 Hydrothermal CO2 reduction using biomass derivatives as reductants
A1 Anderez Fernández, María
A1 Pérez, Eduardo
A1 Martín Martínez, Ángel
A1 Bermejo Roda, Maria Dolores
K1 Glucosa
K1 Hidrogenación
K1 Glucose
K1 Hydrogenation
AB A wide range of organic substances, potentially derived from biomass, were tested as reductants for CO2 (as NaHCO3) in hydrothermal media. The reactions were carried out in batch reactors at 300 °C and 3 h. All the substances reduced CO2 to formic acid in yields up to 65%. These results agree to the mechanisms proposed in literature that suggested that reduction is carried out by primary or secondary alcohols. However, some substances without these groups gave significant yields to formic acid so new mechanisms were proposed. Out of all the compounds tested, glucose gave the highest yield to formic acid, probably due to its particular reaction pathways at the studied conditions. Effect of NaOH in the reaction using glucose was investigated to assure that formic acid is produced from bicarbonate. For ethanol and ethylenglycol, additional conditions were tested to study the dependence of the reaction with time and temperature.
PB Elsevier
YR 2018
FD 2018
LK http://uvadoc.uva.es/handle/10324/33199
UL http://uvadoc.uva.es/handle/10324/33199
LA eng
NO The Journal of Supercritical Fluids, 2018, Volume 133, Part 2,Pages 658-664
NO Producción Científica
DS UVaDOC
RD 27-dic-2024