RT info:eu-repo/semantics/article T1 Designing the Macrocyclic Dimension in Main Group Chemistry A1 Niu, Hao-Che A1 Plajer, Alex J. A1 García Rodríguez, Raúl A1 Singh, Sanjay A1 Wright, Dominic Simon K1 Química orgánica K1 Macromoléculas K1 Organic chemistry K1 Macromolecules AB Outside the confines and well‐established domain of organic chemistry, the systematic building of large macromolecular arrangements based on non‐carbon elements represents a significant and exciting challenge. Our aim in the past two decades has been to develop robust synthetic methods to construct new types of main group architectures in a methodical way, principles of design that parallel those used in the organic arena. This Concept article addresses the fundamental thermodynamic and kinetic problems involved in the design and synthesis of main group macrocycles and looks to future developments of macromolecules in this area, as well as new applications in coordination chemistry. PB Wiley SN 0947-6539 YR 2018 FD 2018 LK http://uvadoc.uva.es/handle/10324/33400 UL http://uvadoc.uva.es/handle/10324/33400 LA eng NO Chemistry A European Journal, 2018, Volume24, Issue13, Pages 3073-3082 NO Producción Científica DS UVaDOC RD 28-nov-2024