RT info:eu-repo/semantics/article
T1 Postfunctionalization of Tris(pyridyl) Aluminate Ligands: Chirality, Coordination, and Supramolecular Chemistry
A1 García Romero, Álvaro
A1 Plajer, Alex J.
A1 Álvarez Miguel, Lucía
A1 Bond, Andrew D.
A1 Wright, Dominic Simon
A1 García Rodríguez, Raúl
K1 Química supramolecular
K1 Supramolecular Chemistry
AB Postfunctionalization of the aluminate anion [EtAl(6‐Me‐2‐py)3]− (1) (2‐py=2‐pyridyl) with alkoxide ligands can be achieved by the selective reactions of the lithium salt 1 Li with alcohols in the appropriate stoichiometry. This method can be used to introduce 3‐ and 4‐py functionality in the form of 3‐ and 4‐alkoxymethylpyridyl groups, while maintaining the integrity of the aluminate framework, thereby giving entry to new supramolecular chemistry. Chirality can be introduced either by using a chiral alcohol as a reactant or by the stepwise reaction of 1 Li with two different nonchiral alcohols. The latter route has allowed the synthesis of a rare example of a chiral‐at‐aluminium aluminate.
PB Wiley
SN 0947-6539
YR 2018
FD 2018
LK http://uvadoc.uva.es/handle/10324/33405
UL http://uvadoc.uva.es/handle/10324/33405
LA eng
NO Chemistry  A European Journal, 2018, Volume 24, Issue 64, Pages 17019-17026
NO Producción Científica
DS UVaDOC
RD 22-dic-2024