RT info:eu-repo/semantics/article
T1 Supramolecular aggregates of metallo–organic acids with stilbazoles. Formation of columnar mesophases and Langmuir films
A1 Domínguez, Cristina
A1 Donnio, Bertrand
A1 Coco Cea, Silverio
A1 Espinet Rubio, Pablo
K1 Oro
K1 Enlace de hidrógeno
K1 Cristales líquidos
K1 Gold
K1 Hydrogen bond
K1 Liquid crystals
AB Supramolecular metal complexes formed through hydrogen bonding between tris(3,4,5-decyloxy)stilbazole and several metallo–organic acids of the type [Au(R)(CNC6H4CO2H)] (R = C6F5, C6F4OC10H21), [cis-[MCl2(CNC6H4COOH)2] and [trans-[MI2(CNC6H4COOH)2] (M = Pd, Pt) have been synthesized. All the supramolecular palladium and platinum polycatenar aggregates display a hexagonal columnar mesophase at temperatures close to room temperature. Most of the supramolecular trisalkoxystilbazole complexes exhibit luminescent behaviour. Aggregates of [Au(C6F4OC10H21)(CNC6H4CO2H)] and [trans-[MI2(CNC6H4COOH)2] (M = Pd, Pt) form stable Langmuir films at the air–water interface.
PB Royal Society of Chemistry
SN 1477-9226
YR 2013
FD 2013
LK http://uvadoc.uva.es/handle/10324/33604
UL http://uvadoc.uva.es/handle/10324/33604
LA eng
NO Dalton Transactions, 2013, 42, 15774-15784
NO Producción Científica
DS UVaDOC
RD 26-abr-2024