RT info:eu-repo/semantics/article
T1 Chiral Bifunctional Thioureas and Squaramides Grafted into Old Polymers of Intrinsic Microporosity for Novel Applications
A1 Valle Álvarez, María
A1 Martín, Laura
A1 Maestro Fernández, Alicia
A1 Andrés García, José María
A1 Pedrosa Sáez, Rafael
K1 Organocatálisis
K1 Organocatalysis
K1 Polímeros de microporosidad
K1 Polymers of  microporosity
AB We have prepared different polymeric chiral bifunctional thioureas and squaramides by modification of the very well-known polymers of intrinsic microporosity (PIM), specifically PIM-1 and PIM-CO-1, to be used as recoverable organocatalysts. The installation of the chiral structures into the polymers has been done in two or three steps in high yields. The catalytic activity of the resulting materials has been proved in the stereoselective nitro-Michael addition and in a cascade process, which allows the synthesis of enantioenriched 4H-chromene derivatives. Squaramide II and thiourea III have been used in six cycles maintaining their activity. View Full-Text
PB MDPI
SN 2073-4360
YR 2019
FD 2019
LK http://uvadoc.uva.es/handle/10324/33917
UL http://uvadoc.uva.es/handle/10324/33917
LA eng
NO Polymers 2019, 11(1), 13
NO Producción Científica
DS UVaDOC
RD 22-nov-2024