RT info:eu-repo/semantics/article
T1 [Cu(C6Cl2F3)(tht)]4: An Extremely Efficient Catalyst for the Aryl Scrambling between Palladium Complexes
A1 Pérez Iglesias, María
A1 Lozano Lavilla, Olmo
A1 Casares González, Juan Ángel
K1 Catalysts
K1 Catalizadores
K1 Aryl
K1 Arilo
K1 Palladium Complexes
K1 Complejos de Paladio
K1 [Cu(C6Cl2F3)(tht)]4
AB The copper compound [Cu(C6Cl2F3)(tht)]4 (1) (tht: tetrahydrothiophene)is an excellent catalyst for the trans- to cis- isomerization ofcomplexes [PdAr2(tht)2](Ar: fluoroaryl) and also for the exchange of arylsbetween those palladium complexes. Herein, we also communicate the synthesisand characterization of 1, and some of its derivatives. The x-ray structureof 1 shows a linear chain of copper atoms, supported by fluoroaryl rings.The NMR 19F-DOSY study indicates that this structure is preserved in solutionalthough in equilibrium with other species.
PB ACS Publications
SN 0276-7333
YR 2019
FD 2019
LK http://uvadoc.uva.es/handle/10324/37014
UL http://uvadoc.uva.es/handle/10324/37014
LA eng
NO Organometallics, 2019, vol. 38, n. 4. p. 739-742
NO Producción Científica
DS UVaDOC
RD 19-oct-2024