RT info:eu-repo/semantics/article
T1 Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C–AuI Bonds in [AuRL] Complexes
A1 Pérez Iglesias, María
A1 Espinet Rubio, Pablo
A1 Casares González, Juan Ángel
K1 Protonolysis
K1 Protonolisis
K1 Transmetalation
K1 Transmetalación
K1 Carbon-gold bonds
K1 Enlaces carbono-oro
AB The protonolysis of C–Au bonds in [AuRL] organometallic complexeshas been studied by calorimetry for twelve R groups. The experimental datahave been combined with DFT calculations to obtain Bond Dissociation Energyvalues (BDE). The C–Au BDE values show a good correlation with the correspondingisolobal C–H BDE values. The heat released in the protonolysis of[AuRL] has also been measured for R = Ph and L = P(OPh)3, PPh3, PMe3, PCy3,and IPr, and these values strongly depend on the trans influence of L because of themutual destabilization of the L–Au and Au–C bonds. The enthalpy of thetransmetalation reactions [AuR(PPh3)] + SnIBu3 → [AuI(PPh3)] + SnRBu3 forseven R groups have been measured and compared with the corresponding[AuR(PPh3)] protonolysis.
PB ACS Publications
SN 0020-1669
YR 2018
FD 2018
LK http://uvadoc.uva.es/handle/10324/37022
UL http://uvadoc.uva.es/handle/10324/37022
LA eng
NO Inorganic Chemistry, 2018, vol. 57, n. 17. p. 11193-11200
NO Producción Científica
DS UVaDOC
RD 24-nov-2024