RT info:eu-repo/semantics/article
T1 GC-EoS extension to alkylphosphate imidazolium ionic liquids
A1 Pablo Nisa, Laura de
A1 Sánchez, Francisco A.
A1 Bermejo Roda, Maria Dolores
A1 Pereda, Selva
K1 Ionic liquidsGroup contributionEquation of state1-alkyl-3-methylimidazolium dimethylphosphate1-alkyl-3-methylimidazolium diethylphosphateGC-EoS
AB In this work, the Group Contribution Equation of State (GC-EoS) is extended to model two new ionic liquid families, namely, 1-alkyl-3-methylimidazolium dimethylphosphate ([-MeIm]+[Me2PO4]-) and 1-alkyl-3-methylimidazolium diethylphosphate ([-MeIm]+[Et2PO4]-). Pure group parameters for the functional groups [-MeIm]+[Me2PO4]- and [-MeIm]+[Et2PO4]- and interaction parameters between these groups and the main paraffinic and aromatic subgroups (CH3, CH2, ACH, AC, ACCH3, CH2=CH) were estimated using infinite dilution activity coefficients from literature. In order to evaluate the performance of the new parameters, the model was compared with experimental data on the phase behavior of binary mixtures, showing an average relative deviation of 4.5%.
PB Elsevier
SN 0378-3812
YR 2019
FD 2019
LK http://uvadoc.uva.es/handle/10324/37283
UL http://uvadoc.uva.es/handle/10324/37283
LA eng
NO Fluid Phase Equilibria Volume 479, 15 January 2019, Pages 25-32
NO Producción Científica
DS UVaDOC
RD 23-dic-2024