RT info:eu-repo/semantics/article
T1 d8···d10 RhI···AuI Interactions in Rh 2,6-Xylylisocyanide Complexes with [Au(CN)2]: Bond Analysis and Crystal Effects
A1 Conejo Rodríguez, Verónica
A1 Peñas de Frutos, Marconi Nicolás
A1 Espinet Rubio, Pablo
K1 Chemical interactions
K1 Interacciones químicas
K1 Crystal structures
K1 Estructuras cristalinas
AB The well known [RhL4]n(anion)n structures, with RhI···RhI d8···d8interactions, are replaced by others with RhI···AuI d8···d10interactions such as [{RhL4}{Au(CN)2}] (L = 2,6-Xylylisocyanide) or[{RhL4}{Au(CN)2} {RhL4}{Au2(CN)3}·4(CHCl3)]∞ when the anion is[Au(CN)2]–. Orbital (Rh···Au), coulombic, and inter-unit π-π arylstacking interactions stabilize these crystal structures.
PB Royal Society of Chemistry
SN 1364-548X
YR 2019
FD 2019
LK http://uvadoc.uva.es/handle/10324/38371
UL http://uvadoc.uva.es/handle/10324/38371
LA eng
NO Chemical Communications, 2019, vol. 55, n. 34.  p. 5005-5008
NO Producción Científica
DS UVaDOC
RD 24-nov-2024