RT info:eu-repo/semantics/article
T1 Dual-Tweezer Behavior of an Octapodal Pyrene Porphyrin-Based System as a Host for Fullerenes
A1 Ferrero, Sergio
A1 Barbero San Juan, Héctor
A1 Miguel San José, Daniel
A1 García Rodríguez, Raúl
A1 Álvarez González, Celedonio Manuel
K1 Carbon nanomaterials
K1 Nanomateriales de carbono
K1 Hydrocarbons
K1 Hidrocarburos
K1 Aromatic compounds
K1 Compuestos aromáticos
K1 Nanospheres
K1 Nanoesferas
K1 Pyrrole
K1 Pirrol
AB The incorporation of eight pyrene units in a single porphyrin core exhibits a great synergistic effect, resulting in high affinity toward C60 and C70. This octapyrene porphyrin is easily accessible by a straightforward two-step synthetic approach that involves an octuple Suzuki reaction. The new supramolecular platform can present single- or double-tweezer fullerene hosting behavior. The switch from double- to single-tweezer behavior is triggered by the simple coordination of Zn2+ to the porphyrin. Both the octapyrene porphyrin 2HPOP and its zinc metalloporphyrin analogue ZnPOP show very high affinity for C60 and C70, while simultaneously allowing the discrimination of C70 over C60 in a C60/C70 mixture. The use of 2HPOP and ZnPOP for the enrichment of real fullerene mixtures is also demonstrated.
PB ACS Publications
SN 1520-6904
YR 2019
FD 2019
LK http://uvadoc.uva.es/handle/10324/39916
UL http://uvadoc.uva.es/handle/10324/39916
LA eng
NO The Journal of Organic Chemistry, 2019, vol. 84. p. 6183-6190
NO Producción Científica
DS UVaDOC
RD 27-nov-2024