RT info:eu-repo/semantics/article
T1 Striking Increase in Hole Mobility upon Metal Coordination to Triphenylene Schiff Base Semiconducting Multicolumnar Mesophases
A1 Domingo de la Rubia, Estela de
A1 Folcia, César L.
A1 Ortega, Josu
A1 Etxebarria, Jesús
A1 Termine, Roberto
A1 Golemme, Attilio
A1 Coco Cea, Silverio
A1 Espinet Rubio, Pablo
K1 Molecular interactions
AB This paper reports the synthesis, liquid-crystal behavior, and charge-transport properties in the mesophase of triphenylene Schiff bases and their copper(II), nickel(II), and oxovanadium(IV) complexes. The thermal and electronic properties of the Schiff bases are modulated by coordination to the corresponding metal moieties, which have the ability to self-assemble into linear structures and help the alignment of the triphenylene columns. This produces two kinds of electronically nonconnected columnar regions, one purely organic and one more inorganic. The most remarkable effect is a striking charge mobility enhancement in the metal-containing mesophases, due to the contribution of the more inorganic columns: in comparison to values of hole mobility along the columnar stacking for the purely organic columnar mesophases, on the order of 10–7 cm2 V–1 s–1, these values jump to 1–10 cm2 V–1 s–1 in these hybrid inorganic/organic columnar materials.
PB American Chemical Society
SN 0020-1669
YR 2020
FD 2020
LK http://uvadoc.uva.es/handle/10324/42651
UL http://uvadoc.uva.es/handle/10324/42651
LA eng
NO Inorganic Chemistry, 2020, 59, 15, 10482–10491
NO Producción Científica
DS UVaDOC
RD 18-nov-2024