RT info:eu-repo/semantics/article
T1 An experimental and theoretical study of the coordination and donor properties of tris-2-pyridyl-phosphine ligands
A1 Hanf, Schirin
A1 Colebatch, Annie Louise
A1 Stehr, Philipp
A1 García Rodríguez, Raúl
A1 Hey-Hawkins, Evamarie
A1 Wright, Dominic Simon
K1 Tris-2-pyridyl
K1 Fosfina
K1 23 Química
AB The coordination characteristics and donor/acceptor properties of a series of 2-pyridyl substituted phosphine ligands have been investigated using structural, spectroscopic and DFT calculational studies. A range of different coordination modes are observed in Mo and W carbonyl complexes of tris-2-pyridyl-phosphine ligands of the type P(2-py’) (2-py’ = substituted or unsubstituted 2-pyridyl group), including an unprecedented example exhibiting N,N′,μ2-π coordination. DFT calculations were used to assess the relative donor/acceptor properties of a range of related 2-pyridyl-phosphine ligands with respect to PPh3 and PtBu3.
PB Royal Society of Chemistry
SN 1477-9226
YR 2020
FD 2020
LK http://uvadoc.uva.es/handle/10324/43689
UL http://uvadoc.uva.es/handle/10324/43689
LA eng
NO Dalton Transactions, 2020, vol. 49, n. 16, p. 5312-5322.
NO Producción Científica
DS UVaDOC
RD 22-nov-2024