RT info:eu-repo/semantics/article T1 ExoMars Raman Laser Spectrometer (RLS): development of chemometric tools to classify ultramafic igneous rocks on Mars A1 Veneranda, Marco A1 López Reyes, Guillermo Eduardo A1 Manrique Martínez, José Antonio A1 Sanz Arranz, Aurelio A1 Lalla, Emmanuel Alexis A1 Konstantinidis, Menelaos A1 Moral Inza, Andoni Gaizka A1 Medina García, Jesús A1 Rull Pérez, Fernando K1 Espectroscopia Raman, Quimiometría, Marte, Rocas K1 ExoMars, Espectroscopia Raman, Quimiometría, Rocas Igneas ultramáficas, Marte K1 2103.03 Espectroscopia K1 2104.04 Geología Planetaria K1 2104.07 Planetas K1 2503.03 Geoquímica Exploratoria K1 2506.13 Petrología Ignea y Metamórfica AB This work aims to evaluate whether the multi-point analysis the ExoMars Raman Laser Spectrometer (RLS) will perform on powdered samples could serve to classify ultramafc rocks on Mars. To do so, the RLS ExoMars Simulator was used to study terrestrial analogues of Martian peridotites and pyroxenites by applying the operational constraints of the Raman spectrometer onboard the Rosalind Franklin rover. Besides qualitative analysis, RLS-dedicated calibration curves have been built to estimate the relative content of olivine and pyroxenes in the samples. These semi-quantitative results, combined with a rough estimate of the concentration ratio between clino- and ortho-pyroxene mineral phases, were used to classify the terrestrial analogues. XRD data were fnally employed as reference to validate Raman results. As this preliminary work suggests, ultramafc rocks on Mars could be efectively classifed through the chemometric analysis of RLS data sets. After optimization, the proposed chemometric tools could be applied to the study of the volcanic geological areas detected at the ExoMars landing site (Oxia Planum), whose mineralogical composition and geological evolution have not been fully understood PB Nature Research SN 2045-2322 YR 2020 FD 2020 LK http://uvadoc.uva.es/handle/10324/46255 UL http://uvadoc.uva.es/handle/10324/46255 LA eng NO Scientifc Reports, Octubre 2020, vol. 10, n. 16954. p. 1-14 NO Producción Científica DS UVaDOC RD 26-abr-2024