RT info:eu-repo/semantics/article T1 Hafnium oxide/graphene/hafnium oxide-stacked nanostructures as resistive switching media A1 Kahro, Tauno A1 Tarre, Aivar A1 Käämbre, Tanel A1 Piirsoo, Helle-Mai A1 Kozlova, Jekaterina A1 Ritslaid, Peeter A1 Kasikov, Aarne A1 Jõgiaas, Taivo A1 Vinuesa Sanz, Guillermo A1 Dueñas Carazo, Salvador A1 Castán Lanaspa, María Helena A1 Tamm, Aile A1 Kukli, Kaupo K1 Graphene K1 Grafeno K1 Atomic layer deposition K1 Deposición atómica de capas K1 Hafnium oxide K1 Óxido de hafnio K1 Stacked nanostructures K1 Nanoestructuras apiladas AB Thin HfO2 films were grown by atomic layer deposition on chemical vapor-deposited large-area graphene. The graphene was transferred, prior to the deposition of the HfO2 overlayer, to the HfO2 bottom dielectric layer pregrown on the Si/TiN substrate. Either HfCl4 or Hf[N(CH3)(C2H5)]4 was used as the metal precursor for the bottom layer. The O2 plasma-assisted process was applied for growing HfO2 from Hf[N(CH3)(C2H5)]4 also on the top of graphene. To improve graphene transfer, the effects of the surface pretreatments of the as-grown and aged Si/TiN/HfO2 substrates were studied and compared. The graphene layer retained its integrity after the plasma processes. Studies on resistive switching on HfO2-graphene-HfO2 nanostructures revealed that the operational voltage ranges in the graphene-HfO2 stacks were modified together with the ratios between high- and low-resistance states. PB ACS Publications SN 2574-0970 YR 2021 FD 2021 LK http://uvadoc.uva.es/handle/10324/46600 UL http://uvadoc.uva.es/handle/10324/46600 LA eng NO ACS Applied Nano Materials, 2021. In press. 12 p. NO Producción Científica DS UVaDOC RD 22-nov-2024