RT info:eu-repo/semantics/article T1 Influence of liquid-to-biogas ratio and alkalinity on the biogas upgrading performance in a demo scale algal-bacterial photobioreactor A1 Marín de Jesús, David Fernando A1 Ortíz, Antonio A1 Díez Montero, Rubén A1 Uggetti, Enrica A1 García, Joan A1 Lebrero Fernández, Raquel A1 Muñoz Torre, Raúl K1 Algal-bacterial photobioreactor K1 Fotobiorreactor de algas y bacterias K1 Alkalinity K1 Alcalinidad K1 Biogas upgrading K1 Mejora de biogás K1 23 Química K1 33 Ciencias Tecnológicas AB The influence of the liquid-to-biogas ratio (L/G) and alkalinity on methane quality was evaluated in a 11.7 m3 outdoors horizontal semi-closed tubular photobioreactor interconnected to a 45-L absorption column (AC). CO2 concentrations in the upgraded methane ranged from <0.1 to 9.6% at L/G of 2.0 and 0.5, respectively, with maximum CH4 concentrations of 89.7% at a L/G of 1.0. Moreover, an enhanced CO2 removal (mediating a decrease in CO2 concentration from 9.6 to 1.2%) and therefore higher CH4 contents (increasing from 88.0 to 93.2%) were observed when increasing the alkalinity of the AC cultivation broth from 42 ± 1 mg L−1 to 996 ± 42 mg L−1. H2S was completely removed regardless of the L/G or the alkalinity in AC. The continuous operation of the photobioreactor with optimized operating parameters resulted in contents of CO2 (<0.1%–1.4%), H2S (<0.7 mg m−3) and CH4 (94.1%–98.8%) complying with international regulations for methane injection into natural gas grids. PB Elsevier SN 0960-8524 YR 2019 FD 2019 LK https://uvadoc.uva.es/handle/10324/46875 UL https://uvadoc.uva.es/handle/10324/46875 LA eng NO Bioresource Technology, 2019, vol. 280, p. 112-117 NO Producción Científica DS UVaDOC RD 27-dic-2024