RT info:eu-repo/semantics/article
T1 Ultrafast hydrolysis of inulin in supercritical water: Fructooligosaccharides reaction pathway and Jerusalem artichoke valorization
A1 Martínez, Celia M.
A1 Adamovic, Tijana
A1 Cantero Sposetti, Danilo Alberto
A1 Cocero Alonso, María José
K1 Biomass
K1 Biomasa
K1 Biorefinery
K1 Biorrefinería
K1 Fructose
K1 Fructosa
K1 Pyruvaldehyde
K1 Piruvaldehído
AB In a biorefinery approach, inulin and inulin-rich biomass as Jerusalem artichoke (JA) could be transformed into platform chemicals such as fructose and/or pyruvaldehyde. To do so, the FASTSUGARS pilot plant proved to be a promising alternative for the selective conversion of biomass. In this work, inulin and JA were hydrolyzed in supercritical water (SCW) for the first time. Commercial inulin was selected as a model for fructooligosaccharides (FOS) and its reaction pathway in SCW was elucidated. It was found that fructose was the primary product from FOS hydrolysis in SCW, which was then selectively transformed into pyruvaldehyde as reaction time increased. Operating with extremely low reaction times (0.12 s) the sugars selectivity of JA was as high as 76% w/w. In both cases, the production of degradation products such as 5-HMF and acids was very low. Finally, comparing JA results to those from lignocellulosic biomass it was found that higher conversion was achieved in the case of JA due to its inulin-based composition.
PB Elsevier
SN 0926-6690
YR 2019
FD 2019
LK https://uvadoc.uva.es/handle/10324/47545
UL https://uvadoc.uva.es/handle/10324/47545
LA eng
NO Industrial Crops and Products, 2019, vol. 133. p. 72-78
NO Producción Científica
DS UVaDOC
RD 27-dic-2024