RT info:eu-repo/semantics/article
T1 Coordination chemistry of the bench-stable tris-2-pyridyl pnictogen ligands [E(6-Me-2-py)3] (E = As, As O, Sb)
A1 Plajer, Alex J.
A1 Crusius, Daniel
A1 Jethwa, Rajesh B.
A1 García Romero, Álvaro
A1 Bond, Andrew D.
A1 García Rodríguez, Raúl
A1 Wright, Dominic Simon
K1 Tripodal ligands
K1 Ligandos tripodales
K1 Coordination chemistry
K1 Química de coordinación
AB Tripodal ligands with main group bridghead units are well established in coordination chemistry and single-site organometallic catalysis. Although a large number of tris(2-pyridyl) main group ligands [E(2-py)3] (E = main group element, 2-py = 2-pyridyl) spanning across the whole p-block are now synthetically acessible, only limited work has been done on the coordination chemistry on the tris(2-pyridyl) group 15 ligands for the heavier elements (As, Sb). In the current study we investigate the coordination chemistry of the ligand family E(6-Me-2-py)3 (E = As, Sb) and of the As(V) ligand O[double bond, length as m-dash]As(6-Me-2-py)3. The air- and mositure-stability of all of these main group ligands makes them especially attractive in future catalytic applications.
PB Royal Society of Chemistry
SN 1477-9234
YR 2021
FD 2021
LK https://uvadoc.uva.es/handle/10324/49353
UL https://uvadoc.uva.es/handle/10324/49353
LA eng
NO Dalton Transactions, 2021, vol. 50, n. 7. p. 2393-2402
NO Producción Científica
DS UVaDOC
RD 23-dic-2024