RT info:eu-repo/semantics/article
T1 Synthesis of tris(3-pyridyl)aluminate ligand and its unexpected stability against hydrolysis: revealing cooperativity effects in heterobimetallic pyridyl aluminates
A1 García Romero, Álvaro
A1 Martín Álvarez, José Miguel
A1 Colebatch, Annie Louise
A1 Plajer, Alex J.
A1 Miguel San José, Daniel
A1 Álvarez González, Celedonio Manuel
A1 García Rodríguez, Raúl
K1 Metallic anions
K1 Aniones metálicos
AB We report the elusive metallic anion [EtAl(3-py)3]− (3-py = 3-pyridyl) (1), the first member of the anionic tris(3-pyridyl) family. Unexpectedly, the lithium complex 1Li shows substantial protic stability against water and alcohols, unlike related tris(2-pyridyl)aluminate analogues. This stability appears to be related to the inability of the [EtAl(3-py)3]− anion to chelate Li+, which precludes a decomposition pathway involving Li/Al cooperativity.
PB Royal Society of Chemistry
SN 1477-9234
YR 2021
FD 2021
LK https://uvadoc.uva.es/handle/10324/49357
UL https://uvadoc.uva.es/handle/10324/49357
LA eng
NO Dalton Transactions, 2021, vol. 50, n. 37. p. 13059-13065
NO Producción Científica
DS UVaDOC
RD 22-dic-2024