RT info:eu-repo/semantics/article
T1 An innovative approach for the generation of species of the interstellar medium
A1 Kolesnikova, Lucie
A1 León Ona, Iker
A1 Alonso Alonso, Elena Rita
A1 Mata, Santiago
A1 Alonso Hernández, José Luis
K1 Chemical synthesis
K1 Interstellar medium
K1 Laser ablation
K1 Molecular generation
K1 Rotational spectroscopy
K1 23 Química
K1 22 Física
K1 2210 Química Física
AB The large amount of unstable species in the realm ofinterstellar chemistry drives an urgent need to develop efficientmethods for the in situ generations of molecules that enabletheir spectroscopic characterizations. Such laboratory experi-ments are fundamental to decode the molecular universe bymatching the interstellar and terrestrial spectra. We propose anapproach based on laser ablation of nonvolatile solid organicprecursors. The generated chemical species are cooled ina supersonic expansion and probed by high-resolution micro-wave spectroscopy. We present a proof of concept througha simultaneous formation of interstellar compounds and thefirst generation of aminocyanoacetylene using diaminomaleo-nitrile as a prototypical precursor. With this micro-laboratory,we open the door to generation of unsuspected species usingprecursors not typically accessible to traditional techniquessuch as electric discharge and pyrolysis.
PB Wiley
SN 1433-7851
YR 2021
FD 2021
LK https://uvadoc.uva.es/handle/10324/51178
UL https://uvadoc.uva.es/handle/10324/51178
LA eng
NO Angewandte Chemie International Edition, 2021, vol. 60, n. 46, p. 24461-24466
NO Producción Científica
DS UVaDOC
RD 12-sep-2024