RT info:eu-repo/semantics/article
T1 From urea to melamine cyanurate: Study of a class of thermal condensation routes for the preparation of graphitic carbon nitride
A1 Chamorro Posada, Pedro
A1 Dante, Roberto C.
A1 Vázquez Cabo, José
A1 Dante, Denisse G.
A1 Martín Ramos, Pablo
A1 Rubiños López, Óscar
A1 Sánchez Arévalo, Francisco M.
K1 Carbon nitride
K1 Nitruro de carbono
K1 Luminescence properties
K1 Propiedades luminiscentes
K1 Melamine cyanurate
K1 Cianurato de melamina
AB This work presents a survey of the intermediates in the well-known thermal synthesis of graphitic carbon nitride from urea. The analysis of the crystalline phases depicts a successive transformation of the precursor into different substances previously used as starting reactants, whereby melamine cyanurate arises as the ultimate precursor of a class of thermal condensation routes to obtain graphitic carbon nitride. The study of the optical properties of the synthesized materials evidences the simultaneous production of an amorphous phase with a significant presence of melon oligomers. These results are also supported by the further characterization of the materials performed using THz-TDS, FT-IR, HRTEM, and XPS techniques, and by theoretical studies conducted using semi-empirical quantum chemistry methods.
PB Elsevier
SN 0022-4596
YR 2022
FD 2022
LK https://uvadoc.uva.es/handle/10324/52513
UL https://uvadoc.uva.es/handle/10324/52513
LA eng
NO Journal of Solid State Chemistry, 2022, vol. 310, 123071
NO Producción Científica
DS UVaDOC
RD 22-nov-2024