RT info:eu-repo/semantics/article T1 Photosynthetic upgrading of biogas from anaerobic digestion of mixed sludge in an outdoors algal-bacterial photobioreactor at pilot scale A1 Méndez, Lara A1 García, Dimas A1 Pérez, Enrique A1 Blanco, Saúl A1 Muñoz Torre, Raúl K1 Photobioreactors K1 Fotobioreactores K1 Biogas K1 Biogás K1 Biomethane K1 Biometano AB Anaerobic digestion can biotransform the biodegradable fraction of sewage sludge into biogas, while the symbiotic action of algal-bacterial consortia can remove both the CO2 and H2S from biogas and nutrients from digestate. A 100 L anaerobic digester operated at 20 days of retention time coupled with a 180 L high-rate algal pond (HRAP) engineered to upgrade the biogas and treat the liquid fraction of the pilot digester was optimized along four operational stages: (I) operation with a greenhouse during winter; (II) operation without greenhouse; (III) process supplementation with NaHCO3; (IV) process supplementation with Na2CO3. The biogas produced was composed of 63.7 ± 2.9% CH4, 33.7 ± 1.9% CO2, 0.5 ± 0.3% O2 and 1.6 ± 1.1% N2. An average methane productivity of 324.7 ± 75.8 mL CH4 g VSin−1 and total COD removals of 48 ± 20% were recorded in the digester. The CH4 concentration in the biomethane gradually decreased to 87.6 ± 2.0% and 85.1 ± 1.3% at the end of stage I and II, respectively, attributed to the loss of inorganic carbon in the HRAP. The supplementation of NaHCO3 and Na2CO3 mediated an increase in the CH4 content to 90.4 ± 1.5 and 91.2 ± 0.7% in stages III and IV, respectively. Steady state CO2 removals of 90% and 88% in stages I and II, and 95.7 and 97.6% in stages III and IV, respectively, were recorded. A constant biomass productivity of 22 g m−2 d−1, set by daily harvesting 26.5 g dry algal-bacterial biomass from the bottom of the settler, was maintained concomitantly with a complete removal of the N and P supplied via centrate. PB Elsevier SN 2214-7144 YR 2022 FD 2022 LK https://uvadoc.uva.es/handle/10324/53596 UL https://uvadoc.uva.es/handle/10324/53596 LA eng NO Journal of Water Process Engineering, 2022, vol. 48, 102891 NO Producción Científica DS UVaDOC RD 25-abr-2024