RT info:eu-repo/semantics/article
T1 Self-resetting bistable redox molecular machines for fullerene recognition
A1 Sacristán Martín, Adriana
A1 Miguel San José, Daniel
A1 Barbero San Juan, Héctor
A1 Álvarez González, Celedonio Manuel
K1 Aromatic compounds
K1 Compuestos aromáticos
K1 Carbon nanomaterials
K1 Nanomateriales de carbono
K1 Chemical structure
K1 Estructura química
K1 Nanospheres
K1 Nanoesferas
AB Addressing control over molecular machines resulting in variable output modulation by mimicking nature mechanisms is a current hot topic. The exploitation of reversibility in thiol/disulfide motifs in chemical systems flanked by nonplanar corannulene moieties capable to recognize fullerenes is presented herein. Two redox-based machines have been conceived for this purpose: an ON/OFF switch that activates its binding properties upon dimerization and a self-resetting (i.e., with an automated backward process) host that substantially modulates its affinity.
PB American Chemical Society
SN 1523-7052
YR 2022
FD 2022
LK https://uvadoc.uva.es/handle/10324/54595
UL https://uvadoc.uva.es/handle/10324/54595
LA eng
NO Organic Letters, 2022, vol. 24, n. 32. p. 5879–5883
NO Producción Científica
DS UVaDOC
RD 16-ago-2024