RT info:eu-repo/semantics/article T1 Surface and microstructural failures of PET-Coated ECCS plates by salmon-polymer interaction A1 Zumelzu, Ernesto A1 Wehrhahn, María A1 Rull Pérez, Fernando A1 Pesenti, Héctor A1 Sanz Arranz, José Aurelio A1 Ugarte, Ricardo K1 Salmon K1 packaging K1 Metal-polymer K1 Layers K1 Failure diagnostics K1 Characterization K1 22 Física K1 23 Química AB The new types of knowledge-intensive, multilayer containers consist of steel plates protected against corrosion by nanometric electrolytic chromium (Cr0) and chromium oxide (Cr2O3) layers chemically bonded to polyethylene terephthalate (PET) polymer coating to preserve food. It was observed that after emptying the cans, the salmon adhered to the polymer coating, changing its color, and that this adhesion increased with longer storage times. This work was aimed at determining the product-container interactions and their characterization by X-ray diffraction (XRD), confocal Raman and micro-Raman imaging and scanning electron microscopy (SEM) analysis. The zones of adhesion showed surface changes, variations in crystallinity and microstructural degradation of the PET coating. In addition, localized damages altering the functional properties of the multilayer system were observed as microcracking in the chromium layers that protect the steel. The degradation undergone was evaluated and characterized at a surface and microstructural level to establish the failure mechanisms, which were mainly associated with the activity of the adhered muscle and its biochemical components. Finally, a recommendation is done to preserve the useful life and functionality of cans for the preservation and efficient use of resources with an impact on recycling and environmental conservancy. PB MDPI YR 2016 FD 2016 LK https://uvadoc.uva.es/handle/10324/57322 UL https://uvadoc.uva.es/handle/10324/57322 LA eng NO Metals, 2016, vol. 6,n. 3, p. 59 NO Producción Científica DS UVaDOC RD 25-nov-2024