RT info:eu-repo/semantics/article
T1 Polymer materials derived from the SEAr reaction for gas separation applications
A1 Matesanz Niño, Laura
A1 Esteban Hernández, Isabel Noelia
A1 Webb, Matthew T.
A1 Martínez Gómez, Aránzazu
A1 Suárez García, Fabián
A1 González Ortega, Alfonso
A1 Miguel García, Jesús Ángel
A1 Palacio Martínez, Laura
A1 Galizia, Michele
A1 Álvarez, Cristina
A1 Lozano, Ángel E.
K1 Polymers
K1 Polimeros y polimerización
K1 Porous materials
K1 Strength of materials
K1 Resistencia de los materiales
K1 Gases - Separation
K1 SEAr polycondensation reaction
K1 Mixed matrix membranes
AB A set of linear polymers were synthesized utilizing an electrophilic aromatic substitution reaction (SEAr) between biphenyl and ketone containing electron-withdrawing groups (isatin, IS; N-methylisatin, MeIS; and 4,5-diazafluoren-9-one, DF). Optimization of the polycondensation reaction was made to obtain high molecular weight products when using DF, which has not previously been used for linear polymer synthesis. Due to the absence of chemically labile units, these polymers exhibited excellent chemical and thermal stability. Linear SEAr polymers were blended with porous polymer networks derived from IS and MeIS, and both neat/mixed materials were tested as membranes for gas separation. The gas separation properties of both pristine polymers and mixed matrix membranes were good, showing some polymer membrane CO2 permeability values higher than 200 barrer.
PB Elsevier
SN 0032-3861
YR 2023
FD 2023
LK https://uvadoc.uva.es/handle/10324/59263
UL https://uvadoc.uva.es/handle/10324/59263
LA eng
NO Polymers, 2023, Vol. 267, Nº. 13, 125647
NO Producción Científica
DS UVaDOC
RD 22-nov-2024