RT info:eu-repo/semantics/article
T1 Pd/Cu bimetallic catalysis to access highly fluorinated biaryls from aryl halides and fluorinated arenes
A1 Ponce de León Pintado, Jaime
A1 Marcos Ayuso, Guillermo
A1 Casares González, Juan Ángel
A1 Espinet Rubio, Pablo
K1 Bimetallic catalysis
K1 Catálisis bimetálica
K1 23 Química
AB An efficient Pd/Cu bimetallic cross-coupling catalysis of fluoroaryl halides and fluoroarenes is reported. In situ generation of the Cu nucleophile by rate determining C–H activation of highly fluorinated aryls (≥4 F atoms) leads to high cross-coupling selectivity with little formation of homocoupling products.
PB Royal Society of Chemistry
SN 1359-7345
YR 2022
FD 2022
LK https://uvadoc.uva.es/handle/10324/59421
UL https://uvadoc.uva.es/handle/10324/59421
LA eng
NO Chemical Communications, 2022, 58, 3146–3149
NO Producción Científica
DS UVaDOC
RD 22-dic-2024