RT info:eu-repo/semantics/article
T1 Selective synthesis of fluorinated biaryls by [MCl2(PhPEWO-F)] (M = Ni, Pd) catalysed Negishi cross-coupling
A1 Ponce de León Pintado, Jaime
A1 Espinet Rubio, Pablo
K1 Negishi cross-coupling
K1 Acoplamiento de Negishi
K1 Cross-coupling reaction catalyzed
K1 Reacción de acoplamiento cruzado
K1 23 Química
AB Highly selective cross-couplings to polyfluorinated assymmetric biaryls, including the symmetric biaryl C6F5–C6F5, are achieved at relatively low temperature (80 °C) and in short times using [MCl2(PhPEWO-F)] catalysts (M = Ni, Pd; PhPEWO-F = 1-(PPh2), 2-(CH[double bond, length as m-dash]CH–C(O)Ph)–C6F4), ArFI, and Zn(C6F5)2 as example of highly fluorinated nucleophile.
PB Royal Society of Chemistry
SN 1359-7345
YR 2021
FD 2021
LK https://uvadoc.uva.es/handle/10324/59422
UL https://uvadoc.uva.es/handle/10324/59422
LA eng
NO Chemical Communications, 2021, 57, 10875–10878
NO Producción Científica
DS UVaDOC
RD 22-dic-2024