RT info:eu-repo/semantics/article T1 Influence of carbon-coated zero-valent iron-based nanoparticle concentration on continuous photosynthetic biogas upgrading A1 Hoyos, Edwin G. A1 Amo Duodu, Gloria A1 Gulsum Kiral, U. A1 Vargas Estrada, Laura A1 Lebrero Fernández, Raquel A1 Muñoz Torre, Raúl K1 Renewable and Green Energy K1 Mass transfer K1 Biogas upgrading K1 Nanoparticles K1 Microalgae productivity K1 Mejora del biogás K1 Nanopartículas K1 Mejora de la fotosíntesis K1 3303.06 Tecnología de la Combustión K1 2406.03 Bioenergética AB This study assessed the influence of carbon-coated zero-valent nanoparticle concentration (70, 140 and 280 mg L−1) on the performance of photosynthetic biogas upgrading in an indoor pilot scale plant composed of an algal-bacterial photobioreactor interconnected to an external biogas absorption column. In addition, the influence of nanoparticle concentration on the abiotic CO2 gas-liquid mass transfer in the biogas absorption column was also evaluated. Microalgae productivity was enhanced by > 100 % when nanoparticles were added to the cultivation broth, which also boosted nitrogen and phosphorus assimilation from centrate. The biomethane produced complied with most international standards only when nanoparticles were supplemented, achieving CO2 concentrations < 1 % (CO2 removal efficiencies > 98 %) and CH4 concentrations > 94 % in the treated biogas. Finally, this research consistently demonstrated that the improvement of biogas upgrading performance by the addition of nanoparticles was based on a photosynthesis enhancement or stimulation (which significantly increased the pH in the algal cultivation broth) rather than on an improved nanoparticle-mediated CO2 capture in the biogas absorption column. PB Elsevier SN 0016-2361 YR 2024 FD 2024 LK https://uvadoc.uva.es/handle/10324/61483 UL https://uvadoc.uva.es/handle/10324/61483 LA eng NO Fuel, 2024, vol. 356, 129610 NO Producción Científica DS UVaDOC RD 24-nov-2024